A porous and interpenetrated metal-organic framework comprising tetranuclear iron III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks

Sang Beom Choi; Min Jeong Seo; Miyoung Cho; Yunjeong Kim; Mi Kyung Jin; Duk Young Jung; Jung Sik Choi; Wha Seung Ahn; Jesse L.C. Rowsell; Jaheon Kim

doi:10.1021/cg070640e

A porous and interpenetrated metal-organic framework comprising tetranuclear iron ^III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks

Sang Beom Choi
, Min Jeong Seo
, Miyoung Cho
, Yunjeong Kim
, Mi Kyung Jin
, Duk Young Jung
, Jung Sik Choi
, Wha Seung Ahn
, Jesse L.C. Rowsell
, Jaheon Kim

Research output: Contribution to journal › Article › peer-review

100 Citations (Scopus)

Abstract

A porous metal-organic framework (MOF), Fe ₄(μ ₃-O) ₂(BTB) _8/3(DMF) ₂(H ₂O) · (DMF) ₁₀(H ₂O) ₂ (1) (BTB = benzene-1,3,5- tribenzoate, DMF = N,N-dimethylformamide) has two interpenetrating 3D frameworks composed of fused cages and shows a stronger affinity for CO ₂ than most other known highly porous MOFs. The unique tetranuclear iron-oxo clusters act as 8-connectors, which are linked by 3-connecting BTBs, to give a partially augmented the net (using the symbolism of O'Keeffe and co-workers). The underlying implications for (3,8)-coordinated networks are also discussed in relation to the framework structure of 1.

Original language	English
Pages (from-to)	2290-2293
Number of pages	4
Journal	Crystal Growth and Design
Volume	7
Issue number	11
DOIs	https://doi.org/10.1021/cg070640e
Publication status	Published - Nov 2007

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10.1021/cg070640e

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Choi, S. B., Seo, M. J., Cho, M., Kim, Y., Jin, M. K., Jung, D. Y., Choi, J. S., Ahn, W. S., Rowsell, J. L. C., & Kim, J. (2007). A porous and interpenetrated metal-organic framework comprising tetranuclear iron ^III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks. Crystal Growth and Design, 7(11), 2290-2293. https://doi.org/10.1021/cg070640e

@article{4b1b743fdf214f13baffc74fecc182b6,

title = "A porous and interpenetrated metal-organic framework comprising tetranuclear iron III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks",

abstract = "A porous metal-organic framework (MOF), Fe 4(μ 3-O) 2(BTB) 8/3(DMF) 2(H 2O) · (DMF) 10(H 2O) 2 (1) (BTB = benzene-1,3,5- tribenzoate, DMF = N,N-dimethylformamide) has two interpenetrating 3D frameworks composed of fused cages and shows a stronger affinity for CO 2 than most other known highly porous MOFs. The unique tetranuclear iron-oxo clusters act as 8-connectors, which are linked by 3-connecting BTBs, to give a partially augmented the net (using the symbolism of O'Keeffe and co-workers). The underlying implications for (3,8)-coordinated networks are also discussed in relation to the framework structure of 1.",

author = "Choi, \{Sang Beom\} and Seo, \{Min Jeong\} and Miyoung Cho and Yunjeong Kim and Jin, \{Mi Kyung\} and Jung, \{Duk Young\} and Choi, \{Jung Sik\} and Ahn, \{Wha Seung\} and Rowsell, \{Jesse L.C.\} and Jaheon Kim",

year = "2007",

month = nov,

doi = "10.1021/cg070640e",

language = "English",

volume = "7",

pages = "2290--2293",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "11",

}

Choi, SB, Seo, MJ, Cho, M, Kim, Y, Jin, MK, Jung, DY, Choi, JS, Ahn, WS, Rowsell, JLC & Kim, J 2007, 'A porous and interpenetrated metal-organic framework comprising tetranuclear iron ^III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks', Crystal Growth and Design, vol. 7, no. 11, pp. 2290-2293. https://doi.org/10.1021/cg070640e

A porous and interpenetrated metal-organic framework comprising tetranuclear iron ^III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks. / Choi, Sang Beom; Seo, Min Jeong; Cho, Miyoung et al.
In: Crystal Growth and Design, Vol. 7, No. 11, 11.2007, p. 2290-2293.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A porous and interpenetrated metal-organic framework comprising tetranuclear iron III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks

AU - Choi, Sang Beom

AU - Seo, Min Jeong

AU - Cho, Miyoung

AU - Kim, Yunjeong

AU - Jin, Mi Kyung

AU - Jung, Duk Young

AU - Choi, Jung Sik

AU - Ahn, Wha Seung

AU - Rowsell, Jesse L.C.

AU - Kim, Jaheon

PY - 2007/11

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N2 - A porous metal-organic framework (MOF), Fe 4(μ 3-O) 2(BTB) 8/3(DMF) 2(H 2O) · (DMF) 10(H 2O) 2 (1) (BTB = benzene-1,3,5- tribenzoate, DMF = N,N-dimethylformamide) has two interpenetrating 3D frameworks composed of fused cages and shows a stronger affinity for CO 2 than most other known highly porous MOFs. The unique tetranuclear iron-oxo clusters act as 8-connectors, which are linked by 3-connecting BTBs, to give a partially augmented the net (using the symbolism of O'Keeffe and co-workers). The underlying implications for (3,8)-coordinated networks are also discussed in relation to the framework structure of 1.

AB - A porous metal-organic framework (MOF), Fe 4(μ 3-O) 2(BTB) 8/3(DMF) 2(H 2O) · (DMF) 10(H 2O) 2 (1) (BTB = benzene-1,3,5- tribenzoate, DMF = N,N-dimethylformamide) has two interpenetrating 3D frameworks composed of fused cages and shows a stronger affinity for CO 2 than most other known highly porous MOFs. The unique tetranuclear iron-oxo clusters act as 8-connectors, which are linked by 3-connecting BTBs, to give a partially augmented the net (using the symbolism of O'Keeffe and co-workers). The underlying implications for (3,8)-coordinated networks are also discussed in relation to the framework structure of 1.

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SN - 1528-7483

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 11

ER -

A porous and interpenetrated metal-organic framework comprising tetranuclear iron ^III-oxo clusters and tripodal organic carboxylates and its implications for (3,8)-coordinated networks

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