Appearance of a Kinetic Compensation Effect in the Acid‐Catalyzed Hydrolysis of Disaccharides

J. W. RHIM; R. V. NUNES; V. A. JONES; K. R. SWARTZEL

doi:10.1111/j.1365-2621.1989.tb08608.x

Appearance of a Kinetic Compensation Effect in the Acid‐Catalyzed Hydrolysis of Disaccharides

J. W. RHIM
, R. V. NUNES
, V. A. JONES
, K. R. SWARTZEL

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A kinetic compensation effect was observed for acid‐catalyzed hydrolysis of a series of disaccharides. Twelve data sets for acid hydrolysis of three disaccharides reported in the literature were analyzed and compensation parameters were determined. The results are well described by following empirical compensation expression: In k_o= AE_a+ B with A = 1.241 and B = ‐2.317. The isokinetic temperature calculated from this compensation relationship was 132.4°C which was located beyond experimental temperature ranges.

Original language	English
Pages (from-to)	222-223
Number of pages	2
Journal	Journal of Food Science
Volume	54
Issue number	1
DOIs	https://doi.org/10.1111/j.1365-2621.1989.tb08608.x
Publication status	Published - Jan 1989

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abstract = "A kinetic compensation effect was observed for acid‐catalyzed hydrolysis of a series of disaccharides. Twelve data sets for acid hydrolysis of three disaccharides reported in the literature were analyzed and compensation parameters were determined. The results are well described by following empirical compensation expression: In ko= AEa+ B with A = 1.241 and B = ‐2.317. The isokinetic temperature calculated from this compensation relationship was 132.4°C which was located beyond experimental temperature ranges.",

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AU - JONES, V. A.

AU - SWARTZEL, K. R.

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N2 - A kinetic compensation effect was observed for acid‐catalyzed hydrolysis of a series of disaccharides. Twelve data sets for acid hydrolysis of three disaccharides reported in the literature were analyzed and compensation parameters were determined. The results are well described by following empirical compensation expression: In ko= AEa+ B with A = 1.241 and B = ‐2.317. The isokinetic temperature calculated from this compensation relationship was 132.4°C which was located beyond experimental temperature ranges.

AB - A kinetic compensation effect was observed for acid‐catalyzed hydrolysis of a series of disaccharides. Twelve data sets for acid hydrolysis of three disaccharides reported in the literature were analyzed and compensation parameters were determined. The results are well described by following empirical compensation expression: In ko= AEa+ B with A = 1.241 and B = ‐2.317. The isokinetic temperature calculated from this compensation relationship was 132.4°C which was located beyond experimental temperature ranges.

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Appearance of a Kinetic Compensation Effect in the Acid‐Catalyzed Hydrolysis of Disaccharides

Abstract

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