Cobaltocene adsorption and dissociation on Cu(1 1 1)

Jaewu Choi; P. A. Dowben

doi:10.1016/j.susc.2006.05.013

Cobaltocene adsorption and dissociation on Cu(1 1 1)

Jaewu Choi
, P. A. Dowben

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Photoemission results indicate that the initial adsorption of cobaltocene on Cu(1 1 1) at 150 K leads to molecular fragmentation, but with subsequent cobaltocene exposures, molecular absorption occurs. The molecularly adsorbed species is either adsorbed with only a fraction of molecules adopting a preferential orientation along the surface normal or adsorbed with the molecular axis away from the surface normal. This adsorption behavior is compared to nickelocene and ferrocene adsorption.

Original language	English
Pages (from-to)	2997-3002
Number of pages	6
Journal	Surface Science
Volume	600
Issue number	15
DOIs	https://doi.org/10.1016/j.susc.2006.05.013
Publication status	Published - 1 Aug 2006

Bibliographical note

Funding Information:
This work was supported by the National Science Foundation through grant CHE-0415421 and the NSF “QSPINS” MRSEC (DMR 0213808). The authors would like to thank Neil Boag for a number of very helpful discussions and for a careful reading of the manuscript. This work was undertaken at the Center for Advanced Microstructures and Devices of Louisiana State University and is supported by the Louisiana Board of Regents.

Keywords

Cobaltocene
Molecular adsorption
Organometallics
Photoemission

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10.1016/j.susc.2006.05.013

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title = "Cobaltocene adsorption and dissociation on Cu(1 1 1)",

abstract = "Photoemission results indicate that the initial adsorption of cobaltocene on Cu(1 1 1) at 150 K leads to molecular fragmentation, but with subsequent cobaltocene exposures, molecular absorption occurs. The molecularly adsorbed species is either adsorbed with only a fraction of molecules adopting a preferential orientation along the surface normal or adsorbed with the molecular axis away from the surface normal. This adsorption behavior is compared to nickelocene and ferrocene adsorption.",

keywords = "Cobaltocene, Molecular adsorption, Organometallics, Photoemission",

author = "Jaewu Choi and Dowben, \{P. A.\}",

note = "Funding Information: This work was supported by the National Science Foundation through grant CHE-0415421 and the NSF {\textquotedblleft}QSPINS{\textquotedblright} MRSEC (DMR 0213808). The authors would like to thank Neil Boag for a number of very helpful discussions and for a careful reading of the manuscript. This work was undertaken at the Center for Advanced Microstructures and Devices of Louisiana State University and is supported by the Louisiana Board of Regents.",

year = "2006",

month = aug,

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doi = "10.1016/j.susc.2006.05.013",

language = "English",

volume = "600",

pages = "2997--3002",

journal = "Surface Science",

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TY - JOUR

T1 - Cobaltocene adsorption and dissociation on Cu(1 1 1)

AU - Choi, Jaewu

AU - Dowben, P. A.

N1 - Funding Information: This work was supported by the National Science Foundation through grant CHE-0415421 and the NSF “QSPINS” MRSEC (DMR 0213808). The authors would like to thank Neil Boag for a number of very helpful discussions and for a careful reading of the manuscript. This work was undertaken at the Center for Advanced Microstructures and Devices of Louisiana State University and is supported by the Louisiana Board of Regents.

PY - 2006/8/1

Y1 - 2006/8/1

N2 - Photoemission results indicate that the initial adsorption of cobaltocene on Cu(1 1 1) at 150 K leads to molecular fragmentation, but with subsequent cobaltocene exposures, molecular absorption occurs. The molecularly adsorbed species is either adsorbed with only a fraction of molecules adopting a preferential orientation along the surface normal or adsorbed with the molecular axis away from the surface normal. This adsorption behavior is compared to nickelocene and ferrocene adsorption.

AB - Photoemission results indicate that the initial adsorption of cobaltocene on Cu(1 1 1) at 150 K leads to molecular fragmentation, but with subsequent cobaltocene exposures, molecular absorption occurs. The molecularly adsorbed species is either adsorbed with only a fraction of molecules adopting a preferential orientation along the surface normal or adsorbed with the molecular axis away from the surface normal. This adsorption behavior is compared to nickelocene and ferrocene adsorption.

KW - Cobaltocene

KW - Molecular adsorption

KW - Organometallics

KW - Photoemission

UR - https://www.scopus.com/pages/publications/33746026098

U2 - 10.1016/j.susc.2006.05.013

DO - 10.1016/j.susc.2006.05.013

M3 - Article

AN - SCOPUS:33746026098

SN - 0039-6028

VL - 600

SP - 2997

EP - 3002

JO - Surface Science

JF - Surface Science

IS - 15

ER -

Cobaltocene adsorption and dissociation on Cu(1 1 1)

Abstract

Bibliographical note

Keywords

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