Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO2 capture from synthetic gas containing CO2 and H2

I. K. Shamsudin; I. Idris; A. Abdullah; J. Kim; M. R. Othman

doi:10.1063/1.5117117

Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO₂ capture from synthetic gas containing CO₂ and H₂

I. K. Shamsudin
, I. Idris
, A. Abdullah
, J. Kim
, M. R. Othman

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

7 Citations (Scopus)

Abstract

A well-defined Zr-metal organic framework (UiO-66) was developed using a rapid sol-gel reflux method and activated by solvent exchange, drying and heating. The activation process with an exchangeable guest solvent produced Zr-MOF with high surface area by removal of almost all the guest and terephthalic acid molecules from the pores, thereby enhancing its capacity for adsorption. The results showed that UiO-66 was synthesized in octahedral crystals of n formed s es of 6 63 m with specific surface area of 313 m²/g. The sample, known to exhibit high chemical and thermal stability of up to 500 C demonstrated strong affinity for carbon dioxide with adsorption capacity of 428.7 cc (CO₂) g ¹ at STP. Results from pressure swing adsorption (PSA) experiment with synthesis gas feed mixture containing 15 vol.% of CO₂ and 85 vol.% indicate that the as-synthesized sample has the potential for effective CO₂/H₂ separation.

Original language	English
Title of host publication	6th International Conference on Environment, ICENV 2018
Subtitle of host publication	Empowering Environment and Sustainable Engineering Nexus Through Green Technology
Editors	Derek Chan Juinn Chieh
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735418646
DOIs	https://doi.org/10.1063/1.5117117
Publication status	Published - 23 Jul 2019
Event	6th International Conference on Environment: Empowering Environment and Sustainable Engineering Nexus Through Green Technology, ICENV 2018 - Penang, Malaysia Duration: 11 Dec 2018 → 13 Dec 2018

Publication series

Name	AIP Conference Proceedings
Volume	2124
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	6th International Conference on Environment: Empowering Environment and Sustainable Engineering Nexus Through Green Technology, ICENV 2018
Country/Territory	Malaysia
City	Penang
Period	11/12/18 → 13/12/18

Bibliographical note

Publisher Copyright:
© 2019 Author(s).

Keywords

UiO-66
Zr-MOF
adsorption
carbon dioxide
gas separation
hydrogen
sol-gel

Access to Document

10.1063/1.5117117

Cite this

Shamsudin, I. K., Idris, I., Abdullah, A., Kim, J., & Othman, M. R. (2019). Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO₂ capture from synthetic gas containing CO₂ and H₂. In D. C. J. Chieh (Ed.), 6th International Conference on Environment, ICENV 2018: Empowering Environment and Sustainable Engineering Nexus Through Green Technology Article 020057 (AIP Conference Proceedings; Vol. 2124). American Institute of Physics Inc.. https://doi.org/10.1063/1.5117117

Shamsudin, I. K. ; Idris, I. ; Abdullah, A. et al. / Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO₂ capture from synthetic gas containing CO₂ and H₂. 6th International Conference on Environment, ICENV 2018: Empowering Environment and Sustainable Engineering Nexus Through Green Technology. editor / Derek Chan Juinn Chieh. American Institute of Physics Inc., 2019. (AIP Conference Proceedings).

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title = "Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO2 capture from synthetic gas containing CO2 and H2",

abstract = "A well-defined Zr-metal organic framework (UiO-66) was developed using a rapid sol-gel reflux method and activated by solvent exchange, drying and heating. The activation process with an exchangeable guest solvent produced Zr-MOF with high surface area by removal of almost all the guest and terephthalic acid molecules from the pores, thereby enhancing its capacity for adsorption. The results showed that UiO-66 was synthesized in octahedral crystals of n formed s es of 6 63 m with specific surface area of 313 m2/g. The sample, known to exhibit high chemical and thermal stability of up to 500 C demonstrated strong affinity for carbon dioxide with adsorption capacity of 428.7 cc (CO2) g 1 at STP. Results from pressure swing adsorption (PSA) experiment with synthesis gas feed mixture containing 15 vol.\% of CO2 and 85 vol.\% indicate that the as-synthesized sample has the potential for effective CO2/H2 separation.",

keywords = "UiO-66, Zr-MOF, adsorption, carbon dioxide, gas separation, hydrogen, sol-gel",

author = "Shamsudin, \{I. K.\} and I. Idris and A. Abdullah and J. Kim and Othman, \{M. R.\}",

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Shamsudin, IK, Idris, I, Abdullah, A, Kim, J & Othman, MR 2019, Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO₂ capture from synthetic gas containing CO₂ and H₂. in DCJ Chieh (ed.), 6th International Conference on Environment, ICENV 2018: Empowering Environment and Sustainable Engineering Nexus Through Green Technology., 020057, AIP Conference Proceedings, vol. 2124, American Institute of Physics Inc., 6th International Conference on Environment: Empowering Environment and Sustainable Engineering Nexus Through Green Technology, ICENV 2018, Penang, Malaysia, 11/12/18. https://doi.org/10.1063/1.5117117

Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO₂ capture from synthetic gas containing CO₂ and H₂. / Shamsudin, I. K.; Idris, I.; Abdullah, A. et al.
6th International Conference on Environment, ICENV 2018: Empowering Environment and Sustainable Engineering Nexus Through Green Technology. ed. / Derek Chan Juinn Chieh. American Institute of Physics Inc., 2019. 020057 (AIP Conference Proceedings; Vol. 2124).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO2 capture from synthetic gas containing CO2 and H2

AU - Shamsudin, I. K.

AU - Idris, I.

AU - Abdullah, A.

AU - Kim, J.

AU - Othman, M. R.

PY - 2019/7/23

Y1 - 2019/7/23

N2 - A well-defined Zr-metal organic framework (UiO-66) was developed using a rapid sol-gel reflux method and activated by solvent exchange, drying and heating. The activation process with an exchangeable guest solvent produced Zr-MOF with high surface area by removal of almost all the guest and terephthalic acid molecules from the pores, thereby enhancing its capacity for adsorption. The results showed that UiO-66 was synthesized in octahedral crystals of n formed s es of 6 63 m with specific surface area of 313 m2/g. The sample, known to exhibit high chemical and thermal stability of up to 500 C demonstrated strong affinity for carbon dioxide with adsorption capacity of 428.7 cc (CO2) g 1 at STP. Results from pressure swing adsorption (PSA) experiment with synthesis gas feed mixture containing 15 vol.% of CO2 and 85 vol.% indicate that the as-synthesized sample has the potential for effective CO2/H2 separation.

AB - A well-defined Zr-metal organic framework (UiO-66) was developed using a rapid sol-gel reflux method and activated by solvent exchange, drying and heating. The activation process with an exchangeable guest solvent produced Zr-MOF with high surface area by removal of almost all the guest and terephthalic acid molecules from the pores, thereby enhancing its capacity for adsorption. The results showed that UiO-66 was synthesized in octahedral crystals of n formed s es of 6 63 m with specific surface area of 313 m2/g. The sample, known to exhibit high chemical and thermal stability of up to 500 C demonstrated strong affinity for carbon dioxide with adsorption capacity of 428.7 cc (CO2) g 1 at STP. Results from pressure swing adsorption (PSA) experiment with synthesis gas feed mixture containing 15 vol.% of CO2 and 85 vol.% indicate that the as-synthesized sample has the potential for effective CO2/H2 separation.

KW - UiO-66

KW - Zr-MOF

KW - adsorption

KW - carbon dioxide

KW - gas separation

KW - hydrogen

KW - sol-gel

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DO - 10.1063/1.5117117

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AN - SCOPUS:85070110743

T3 - AIP Conference Proceedings

BT - 6th International Conference on Environment, ICENV 2018

A2 - Chieh, Derek Chan Juinn

PB - American Institute of Physics Inc.

T2 - 6th International Conference on Environment: Empowering Environment and Sustainable Engineering Nexus Through Green Technology, ICENV 2018

Y2 - 11 December 2018 through 13 December 2018

ER -

Shamsudin IK, Idris I, Abdullah A, Kim J, Othman MR. Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO₂ capture from synthetic gas containing CO₂ and H₂. In Chieh DCJ, editor, 6th International Conference on Environment, ICENV 2018: Empowering Environment and Sustainable Engineering Nexus Through Green Technology. American Institute of Physics Inc. 2019. 020057. (AIP Conference Proceedings). doi: 10.1063/1.5117117