Electro-optical and electrochemical properties of an ionic polyacetylene derivative with azobenzene anisole moieties

An ionic polyacetylene derivative with azoanisole moieties was prepared by the activated polymerization of 2-ethynylpyridine by using 4-[4-(9-bromononyloxy)phenylazo]anisole without any additional initiator or catalyst in high yield. The chemical structure of poly[2-ethynyl-N-(p-methoxyphenylazophenyl)oxynonylpyridinium bromide] (PEMPB) was characterized by instrumental methods such as NMR ( ¹H and ¹³C), IR, UV-vis spectroscopies to have a conjugated polymer backbone system with the designed azobenzene moieties as substituents. This polymer was completely soluble in organic solvents and well processible. The electrochemical and electro-optical properties of PEMPB were studied. The cyclovoltammograms of this polymer exhibited the irreversible electrochemical behaviors between the oxidation and reduction peaks. The oxidation current density of PEMPB versus the scan rate is approximately linear relationship in the range of 30mV/s-120mV/s. The exponent of scan rate, x value of PEMPB, is found to be 0.6. The absorption spectrum starts around 700nm and shows a characteristic absorption band at visible region of 464nm due to the π→π*interband transition of the polymer backbone, which is a peak of the conjugated polyene backbone. The photoluminescence spectrum showed that the PL peak is located at 539nm corresponding to the photon energy of 2.30eV.