Fe(III)-catalyzed Oxidative Povarov Reaction with Molecular Oxygen Oxidant

Du Yong Park; Joon Young Hwang; Eun Joo Kang

doi:10.1002/bkcs.12273

Fe(III)-catalyzed Oxidative Povarov Reaction with Molecular Oxygen Oxidant

Du Yong Park
, Joon Young Hwang
, Eun Joo Kang

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The synthesis of tetrahydroquinoline derivatives from dimethyl anilines and enamides has been developed by Fe(III)-phenanthroline complex under aerobic condition. The oxidation of tertiary anilines involving a single electron transfer of Fe(phen)₃(PF₆)₃ afforded the iminium ion intermediate, which reacted with electron-rich alkenes to build a six-membered N-heterocycles containing quaternary carbon center via the oxidative Povarov reaction process.

Original language	English
Pages (from-to)	798-801
Number of pages	4
Journal	Bulletin of the Korean Chemical Society
Volume	42
Issue number	5
DOIs	https://doi.org/10.1002/bkcs.12273
Publication status	Published - May 2021

Bibliographical note

Publisher Copyright:
© 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbH

Keywords

Iminium
Iron(III)–phenanthroline complex
Oxidative Povarov reaction
Oxygen
Tetrahydroquinoline

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10.1002/bkcs.12273

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title = "Fe(III)-catalyzed Oxidative Povarov Reaction with Molecular Oxygen Oxidant",

abstract = "The synthesis of tetrahydroquinoline derivatives from dimethyl anilines and enamides has been developed by Fe(III)-phenanthroline complex under aerobic condition. The oxidation of tertiary anilines involving a single electron transfer of Fe(phen)3(PF6)3 afforded the iminium ion intermediate, which reacted with electron-rich alkenes to build a six-membered N-heterocycles containing quaternary carbon center via the oxidative Povarov reaction process.",

keywords = "Iminium, Iron(III)–phenanthroline complex, Oxidative Povarov reaction, Oxygen, Tetrahydroquinoline",

author = "Park, \{Du Yong\} and Hwang, \{Joon Young\} and Kang, \{Eun Joo\}",

note = "Publisher Copyright: {\textcopyright} 2021 Korean Chemical Society, Seoul \& Wiley-VCH GmbH",

year = "2021",

month = may,

doi = "10.1002/bkcs.12273",

language = "English",

volume = "42",

pages = "798--801",

journal = "Bulletin of the Korean Chemical Society",

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TY - JOUR

T1 - Fe(III)-catalyzed Oxidative Povarov Reaction with Molecular Oxygen Oxidant

AU - Park, Du Yong

AU - Hwang, Joon Young

AU - Kang, Eun Joo

PY - 2021/5

Y1 - 2021/5

N2 - The synthesis of tetrahydroquinoline derivatives from dimethyl anilines and enamides has been developed by Fe(III)-phenanthroline complex under aerobic condition. The oxidation of tertiary anilines involving a single electron transfer of Fe(phen)3(PF6)3 afforded the iminium ion intermediate, which reacted with electron-rich alkenes to build a six-membered N-heterocycles containing quaternary carbon center via the oxidative Povarov reaction process.

AB - The synthesis of tetrahydroquinoline derivatives from dimethyl anilines and enamides has been developed by Fe(III)-phenanthroline complex under aerobic condition. The oxidation of tertiary anilines involving a single electron transfer of Fe(phen)3(PF6)3 afforded the iminium ion intermediate, which reacted with electron-rich alkenes to build a six-membered N-heterocycles containing quaternary carbon center via the oxidative Povarov reaction process.

KW - Iminium

KW - Iron(III)–phenanthroline complex

KW - Oxidative Povarov reaction

KW - Oxygen

KW - Tetrahydroquinoline

UR - https://www.scopus.com/pages/publications/85103577159

U2 - 10.1002/bkcs.12273

DO - 10.1002/bkcs.12273

M3 - Article

AN - SCOPUS:85103577159

SN - 0253-2964

VL - 42

SP - 798

EP - 801

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 5

ER -

Fe(III)-catalyzed Oxidative Povarov Reaction with Molecular Oxygen Oxidant

Abstract

Bibliographical note

Keywords

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