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Flexible organic light-emitting diode with a conductive polymer electrode

  • Mansu Kim
  • , Yoo Sung Lee
  • , Young Chul Kim
  • , Myung Soo Choi
  • , Jun Young Lee

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

We report on a flexible organic light-emitting diode (FOLED) prepared by using a poly(3,4-ethylenedioxythiophene) (PEDOT) anode formed via in-situ polymerization of ethylenedioxythiophene (EDOT) on a polyethersulfone (PES) substrate. Ferric p-toluene sulfonate (FTS) was used as a dopant, and N,N-dimethylacetamide (DMAc) was added to enhance the anode properties. The PEDOT:FTS film polymerized in the presence of DMAc (DMAc-PEDOT:FTS) exhibited better performance than those polymerized without DMAc (Normal-PEDOT:FTS) in terms of both optical transmittance and surface resistance, and the DMAc-PEDOT:FTS film gave a work function of 4.67 eV which is 0.3 eV higher than that of the Normal-PEDOT:FTS film. Optical transmittance and surface resistance of the DMAc-PEDOT:FTS films could be controlled to be 52-87% and 130-390 Ω/sq, respectively. When an optimized DMAc-PEDOT:FTS film was employed as an anode, the Alq3 [(8-hydroxy-quinolinato)-aluminium] based FOLED device exhibited 30% higher luminous efficiency and more than 20 times higher max luminance than the device with the Normal-PEDOT:FTS anode.

Original languageEnglish
Pages (from-to)2318-2322
Number of pages5
JournalSynthetic Metals
Volume161
Issue number21-22
DOIs
Publication statusPublished - Nov 2011

Bibliographical note

Funding Information:
This research was supported by Basic Science Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (grant no. 2010-0028038 ).

Keywords

  • DMAc effect
  • Flexible organic light-emitting diode
  • In-situ polymerization
  • PEDOT:FTS anode

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