Abstract
It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of the polymer could be processed into aqueous emulsions that display high fluorescence quantum yields (see picture).
| Original language | English |
|---|---|
| Pages (from-to) | 7486-7488 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 41 |
| DOIs | |
| Publication status | Published - 4 Oct 2010 |
Keywords
- Biphasic systems
- Emulsions
- Fluorescence
- Perfluorinated solvents
- Polymerization
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