High-quality graphene via microwave reduction of solution-exfoliated graphene oxide

Damien Voiry, Jieun Yang, Jacob Kupferberg, Raymond Fullon, Calvin Lee, Hu Young Jeong, Hyeon Suk Shin, Manish Chhowalla

Research output: Contribution to journalArticlepeer-review

752 Citations (Scopus)

Abstract

Efficient exfoliation of graphite in solutions to obtain high-quality graphene flakes is desirable for printable electronics, catalysis, energy storage, and com posites. Graphite oxide with large lateral dimensions has an exfoliation yield of ∼100%, but it has not been possible to completely remove the oxygen functional groups so that the reduced form of graphene oxide (GO; reduced form: rGO) remains a highly disordered material. Here we report a simple, rapid method to reduce GO into pristine graphene using 1- to 2-second pulses of microwaves.The desirable structural properties are translated intomobility values of >1000 square centimeters per volt per second in fieldeffect transistors with microwave-reduced GO (MW-rGO) as the channelmaterial and into particularly high activity for MW-rGO catalyst support toward oxygen evolution reactions.

Original languageEnglish
Pages (from-to)1413-1416
Number of pages4
JournalScience
Volume353
Issue number6306
DOIs
Publication statusPublished - 23 Sept 2016

Bibliographical note

Funding Information:
M.C. and D.V. acknowledge financial support from NSF Division of Graduate education (grant 0903661) and Electrical, Communications and Cyber Systems (grant 1128335). J.Y., J.K., and M.C. acknowledge financial support from the Rutgers Energy Institute. R.F. acknowledges financial support from the U.S. Department of Education Graduate Assistance in Areas of National Need program (grant P200A120142). C.L. and J.K. acknowledge support from the Rutgers ARESTY Research Assistant program. H.S.S. acknowledges support from the National Research Foundation (NRF) (grant RF 2014R1A2A2A01007136) and from the Center for Advanced Soft Electronics (grant code 2011-0031630) under the Global Frontier Research Program through the NRF funded by the Ministry of Science, ICT and Future Planning, Korea. All data are in the main paper and the supplementary materials.

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