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Low voltage operation of nonvolatile ferroelectric capacitors using poly(vinylidene fluoride-trifluoroethylene) copolymer and thin Al2 O3 insulating layer

  • Soon Won Jung
  • , Sung Min Yoon
  • , Seung Youl Kang
  • , Kyu Jeong Choi
  • , Woong Chul Shin
  • , Byoung Gon Yu

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

We have successfully demonstrated low voltage operation of metal-ferroelectric-insulator-semiconductor (MFIS) capacitors with poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)]/ Al2 O 3 /p-Si (100) structures. P(VDF-TrFE) copolymer thin films (thickness of 20 nm) prepared by the spin-coating method and annealed at 140°C showed good ferroelectric behavior with a remnant polarization of 1 μC/ cm2 at a voltage sweep of ±4 V. Remarkable reduction in leakage current was realized by introducing a 5 nm thick Al2 O 3 layer grown by atomic layer deposition. In capacitance-voltage measurements, MFIS capacitors showed rectangular-shaped hysteresis curves, attributed to the ferroelectric material, in which the memory window width was 1.5 V, even at applied voltages of ±3 V.

Original languageEnglish
Pages (from-to)H325-H328
JournalElectrochemical and Solid-State Letters
Volume12
Issue number9
DOIs
Publication statusPublished - 2009

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