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Microporous membrane formation via thermally-induced phase separation. IV. Effect of isotactic polypropylene crystallization kinetics on membrane structure

  • Gordon B.A. Lim
  • , Sung Soo Kim
  • , Qinhong Ye
  • , Yu Feng Wang
  • , Douglas R. Lloyd

Research output: Contribution to journalArticlepeer-review

137 Citations (Scopus)

Abstract

Non-nucleated and nucleated isotactic polypropylene microporous membranes have been prepared via thermally-induced solid-liquid phase separation of polymer-diluent mixtures. Three linear alkanes and mineral oil were used as the diluents and adipic acid was used as the nucleating agent. The membranes were formed under isothermal and non-isothermal crystallizing conditions. Membrane structures as determined by scanning electron microscope depended on polymer concentration, cooling rate, and the addition of nucleating agent.

Original languageEnglish
Pages (from-to)31-40
Number of pages10
JournalJournal of Membrane Science
Volume64
Issue number1-2
DOIs
Publication statusPublished - 15 Nov 1991

Bibliographical note

Funding Information:
The authors gratefully acknowledge the continued generous financial support of the Central Research Technology Development Laboratory of the 3M Company, St. Paul, MN and the Texas Advanced Technology Program.

Keywords

  • membrane preparation and structure
  • microporous membranes
  • phase separation, thermally-induced

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