Microwave-assisted cyanation of an aryl bromide directly on a metal-organic framework

Min Kim; J. Sergio; Garibay; Seth M. Cohen

doi:10.1021/ic102436b

Microwave-assisted cyanation of an aryl bromide directly on a metal-organic framework

Min Kim
, J. Sergio
, Garibay
, Seth M. Cohen

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr4+-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.

Original language	English
Pages (from-to)	729-731
Number of pages	3
Journal	Inorganic Chemistry
Volume	50
Issue number	3
DOIs	https://doi.org/10.1021/ic102436b
Publication status	Published - 7 Feb 2011

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10.1021/ic102436b

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title = "Microwave-assisted cyanation of an aryl bromide directly on a metal-organic framework",

abstract = "A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr4+-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.",

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AU - Sergio, J.

AU - Garibay,

AU - Cohen, Seth M.

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N2 - A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr4+-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.

AB - A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr4+-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.

UR - https://www.scopus.com/pages/publications/79951636601

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JO - Inorganic Chemistry

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ER -

Microwave-assisted cyanation of an aryl bromide directly on a metal-organic framework

Abstract

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