Mixed-valence states in MMX-chains complex, Pt2(dta)4I

Hiroshi Kitagawa; Noriaki Onodera; Jeung Sun Ahn; Tadaoki Mitani; Misa Kim; Yoshiki Ozawa; Koshiro Toriumi; Kazutomo Yasui; Toshio Manabe; Masahiro Yamashita

doi:10.1080/10587259608030818

Mixed-valence states in MMX-chains complex, Pt₂(dta)₄I

Hiroshi Kitagawa
, Noriaki Onodera
, Jeung Sun Ahn
, Tadaoki Mitani
, Misa Kim
, Yoshiki Ozawa
, Koshiro Toriumi
, Kazutomo Yasui
, Toshio Manabe
, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt₂(dta)₄I (dta = CH₃CS₂) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.

Original language	English
Pages (from-to)	311-316
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Volume	285-286
DOIs	https://doi.org/10.1080/10587259608030818
Publication status	Published - 1996

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title = "Mixed-valence states in MMX-chains complex, Pt2(dta)4I",

abstract = "Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt2(dta)4I (dta = CH3CS2) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.",

author = "Hiroshi Kitagawa and Noriaki Onodera and Ahn, \{Jeung Sun\} and Tadaoki Mitani and Misa Kim and Yoshiki Ozawa and Koshiro Toriumi and Kazutomo Yasui and Toshio Manabe and Masahiro Yamashita",

year = "1996",

doi = "10.1080/10587259608030818",

language = "English",

volume = "285-286",

pages = "311--316",

journal = "Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Mixed-valence states in MMX-chains complex, Pt2(dta)4I

AU - Kitagawa, Hiroshi

AU - Onodera, Noriaki

AU - Ahn, Jeung Sun

AU - Mitani, Tadaoki

AU - Kim, Misa

AU - Ozawa, Yoshiki

AU - Toriumi, Koshiro

AU - Yasui, Kazutomo

AU - Manabe, Toshio

AU - Yamashita, Masahiro

PY - 1996

Y1 - 1996

N2 - Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt2(dta)4I (dta = CH3CS2) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.

AB - Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt2(dta)4I (dta = CH3CS2) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.

UR - https://www.scopus.com/pages/publications/0004421755

U2 - 10.1080/10587259608030818

DO - 10.1080/10587259608030818

M3 - Article

AN - SCOPUS:0004421755

SN - 1058-725X

VL - 285-286

SP - 311

EP - 316

JO - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

ER -

Mixed-valence states in MMX-chains complex, Pt₂(dta)₄I

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