Multinuclear solid-state NMR spectroscopy of a paramagnetic layered double hydroxide

Shinsuke Ishihara; Kenzo Deguchi; Hiroaki Sato; Masatoshi Takegawa; Eisaku Nii; Shinobu Ohki; Kenjiro Hashi; Masataka Tansho; Tadashi Shimizu; Katsuhiko Ariga; Jan Labuta; Pathik Sahoo; Yusuke Yamauchi; Jonathan P. Hill; Nobuo Iyi; Ryo Sasai

doi:10.1039/c3ra44231d

Multinuclear solid-state NMR spectroscopy of a paramagnetic layered double hydroxide

Shinsuke Ishihara
, Kenzo Deguchi
, Hiroaki Sato
, Masatoshi Takegawa
, Eisaku Nii
, Shinobu Ohki
, Kenjiro Hashi
, Masataka Tansho
, Tadashi Shimizu
, Katsuhiko Ariga
, Jan Labuta
, Pathik Sahoo
, Yusuke Yamauchi
, Jonathan P. Hill
, Nobuo Iyi
, Ryo Sasai

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

NMR spectroscopy is rarely utilized when analytes include paramagnetic ions. We show that multinuclear solid-state NMR is actually potentially useful for investigating nanostructures of a layered double hydroxide (LDH) containing paramagnetic Ni²⁺ cations. In particular, ¹³C NMR spectra of interlayer carbonate anions are well resolved by using conventional MAS/DD.

Original language	English
Pages (from-to)	19857-19860
Number of pages	4
Journal	RSC Advances
Volume	3
Issue number	43
DOIs	https://doi.org/10.1039/c3ra44231d
Publication status	Published - 21 Nov 2013

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abstract = "NMR spectroscopy is rarely utilized when analytes include paramagnetic ions. We show that multinuclear solid-state NMR is actually potentially useful for investigating nanostructures of a layered double hydroxide (LDH) containing paramagnetic Ni2+ cations. In particular, 13C NMR spectra of interlayer carbonate anions are well resolved by using conventional MAS/DD.",

author = "Shinsuke Ishihara and Kenzo Deguchi and Hiroaki Sato and Masatoshi Takegawa and Eisaku Nii and Shinobu Ohki and Kenjiro Hashi and Masataka Tansho and Tadashi Shimizu and Katsuhiko Ariga and Jan Labuta and Pathik Sahoo and Yusuke Yamauchi and Hill, \{Jonathan P.\} and Nobuo Iyi and Ryo Sasai",

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T1 - Multinuclear solid-state NMR spectroscopy of a paramagnetic layered double hydroxide

AU - Ishihara, Shinsuke

AU - Deguchi, Kenzo

AU - Sato, Hiroaki

AU - Takegawa, Masatoshi

AU - Nii, Eisaku

AU - Ohki, Shinobu

AU - Hashi, Kenjiro

AU - Tansho, Masataka

AU - Shimizu, Tadashi

AU - Ariga, Katsuhiko

AU - Labuta, Jan

AU - Sahoo, Pathik

AU - Yamauchi, Yusuke

AU - Hill, Jonathan P.

AU - Iyi, Nobuo

AU - Sasai, Ryo

PY - 2013/11/21

Y1 - 2013/11/21

N2 - NMR spectroscopy is rarely utilized when analytes include paramagnetic ions. We show that multinuclear solid-state NMR is actually potentially useful for investigating nanostructures of a layered double hydroxide (LDH) containing paramagnetic Ni2+ cations. In particular, 13C NMR spectra of interlayer carbonate anions are well resolved by using conventional MAS/DD.

AB - NMR spectroscopy is rarely utilized when analytes include paramagnetic ions. We show that multinuclear solid-state NMR is actually potentially useful for investigating nanostructures of a layered double hydroxide (LDH) containing paramagnetic Ni2+ cations. In particular, 13C NMR spectra of interlayer carbonate anions are well resolved by using conventional MAS/DD.

UR - https://www.scopus.com/pages/publications/84886876720

U2 - 10.1039/c3ra44231d

DO - 10.1039/c3ra44231d

M3 - Article

AN - SCOPUS:84886876720

SN - 2046-2069

VL - 3

SP - 19857

EP - 19860

JO - RSC Advances

JF - RSC Advances

IS - 43

ER -

Multinuclear solid-state NMR spectroscopy of a paramagnetic layered double hydroxide

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