Multiple ion cores in anthracene anion clusters

Jae Kyu Song; Nam Ki Lee; Seong Keun Kim

doi:10.1002/anie.200390081

Multiple ion cores in anthracene anion clusters

Jae Kyu Song
, Nam Ki Lee
, Seong Keun Kim

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Spreading the charge: Anion clusters of anthracene, (An)_n^-, with n values of up to 6 were studied and found to contain a distinctly monomeric, dimeric, or trimeric ion core with a delocalized electronic charge (see figure). Coexistence of dimeric and trimeric ion cores was observed in (An)₄^-, but the ion core reverts to a monomeric one in (An)₅^-, with the completion of a solvation shell around the monomer anion.

Original language	English
Pages (from-to)	213-216
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	2
DOIs	https://doi.org/10.1002/anie.200390081
Publication status	Published - 13 Jan 2003

Keywords

Anions
Anthracene
Density functional calculations
Photoelectron spectroscopy

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10.1002/anie.200390081

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KW - Anions

KW - Anthracene

KW - Density functional calculations

KW - Photoelectron spectroscopy

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Multiple ion cores in anthracene anion clusters

Abstract

Keywords

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