Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene

Sven Müller; Woohyeong Lee; Jae Yeong Song; Eunsu Kang; Jung Min Joo

doi:10.1039/d2cc04208h

Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene

Sven Müller
, Woohyeong Lee
, Jae Yeong Song
, Eunsu Kang
, Jung Min Joo

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Pd-catalyzed alkenylations of metallocenes via C-H activation were developed using electronically tunable pyrazolonaphthyridine (PzNPy) ligands. Ferrocene was alkenylated using the most electron-deficient ligand in the series, whereas the less reactive ruthenocene needed balancing of the electrophilicity and stability of catalysts. Various alkenes were installed, allowing fine-tuning of redox potentials.

Original language	English
Pages (from-to)	10809-10812
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	77
DOIs	https://doi.org/10.1039/d2cc04208h
Publication status	Published - 2 Sept 2022

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© 2022 The Royal Society of Chemistry.

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abstract = "Pd-catalyzed alkenylations of metallocenes via C-H activation were developed using electronically tunable pyrazolonaphthyridine (PzNPy) ligands. Ferrocene was alkenylated using the most electron-deficient ligand in the series, whereas the less reactive ruthenocene needed balancing of the electrophilicity and stability of catalysts. Various alkenes were installed, allowing fine-tuning of redox potentials.",

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T1 - Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene

AU - Müller, Sven

AU - Lee, Woohyeong

AU - Song, Jae Yeong

AU - Kang, Eunsu

AU - Joo, Jung Min

PY - 2022/9/2

Y1 - 2022/9/2

N2 - Pd-catalyzed alkenylations of metallocenes via C-H activation were developed using electronically tunable pyrazolonaphthyridine (PzNPy) ligands. Ferrocene was alkenylated using the most electron-deficient ligand in the series, whereas the less reactive ruthenocene needed balancing of the electrophilicity and stability of catalysts. Various alkenes were installed, allowing fine-tuning of redox potentials.

AB - Pd-catalyzed alkenylations of metallocenes via C-H activation were developed using electronically tunable pyrazolonaphthyridine (PzNPy) ligands. Ferrocene was alkenylated using the most electron-deficient ligand in the series, whereas the less reactive ruthenocene needed balancing of the electrophilicity and stability of catalysts. Various alkenes were installed, allowing fine-tuning of redox potentials.

UR - https://www.scopus.com/pages/publications/85138603503

U2 - 10.1039/d2cc04208h

DO - 10.1039/d2cc04208h

M3 - Article

C2 - 36069397

AN - SCOPUS:85138603503

SN - 1359-7345

VL - 58

SP - 10809

EP - 10812

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene

Abstract

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