Novel Ligand Transformations in Cluster Complexes. α-CH Bond Activation In a Secondary Carbene Ligand In a Triosmium Cluster

Richard D. Adams; James E. Babin; Hoon Sik Kim

doi:10.1021/om00140a037

Novel Ligand Transformations in Cluster Complexes. α-CH Bond Activation In a Secondary Carbene Ligand In a Triosmium Cluster

Richard D. Adams, James E. Babin, Hoon Sik Kim

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14 Citations (Scopus)

Abstract

The carbene cluster complex Os₃(CO)₉[C-(H)NMe₂](μ-SPh)(μ-H) (2) has been synthesized in 66% yield by the reaction of Os₃(CO)₁₀(μ-SPh)(μ-H) with CH₂-(NMe₂)₂. Photodecarbonylation of 2 leads to formation of the compound Os₃(CO)₈(μ-C=NMe₂)(μ-SPh)(μ-H) (3) in 37% yield by an a-CH bond activation in the carbene ligand.

Original language	English
Pages (from-to)	1924-1925
Number of pages	2
Journal	Organometallics
Volume	5
Issue number	9
DOIs	https://doi.org/10.1021/om00140a037
Publication status	Published - 1986

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title = "Novel Ligand Transformations in Cluster Complexes. α-CH Bond Activation In a Secondary Carbene Ligand In a Triosmium Cluster",

abstract = "The carbene cluster complex Os3(CO)9[C-(H)NMe2](μ-SPh)(μ-H) (2) has been synthesized in 66% yield by the reaction of Os3(CO)10(μ-SPh)(μ-H) with CH2-(NMe2)2. Photodecarbonylation of 2 leads to formation of the compound Os3(CO)8(μ-C=NMe2)(μ-SPh)(μ-H) (3) in 37% yield by an a-CH bond activation in the carbene ligand.",

author = "Adams, {Richard D.} and Babin, {James E.} and Kim, {Hoon Sik}",

year = "1986",

doi = "10.1021/om00140a037",

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journal = "Organometallics",

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T1 - Novel Ligand Transformations in Cluster Complexes. α-CH Bond Activation In a Secondary Carbene Ligand In a Triosmium Cluster

AU - Adams, Richard D.

AU - Babin, James E.

AU - Kim, Hoon Sik

PY - 1986

Y1 - 1986

N2 - The carbene cluster complex Os3(CO)9[C-(H)NMe2](μ-SPh)(μ-H) (2) has been synthesized in 66% yield by the reaction of Os3(CO)10(μ-SPh)(μ-H) with CH2-(NMe2)2. Photodecarbonylation of 2 leads to formation of the compound Os3(CO)8(μ-C=NMe2)(μ-SPh)(μ-H) (3) in 37% yield by an a-CH bond activation in the carbene ligand.

AB - The carbene cluster complex Os3(CO)9[C-(H)NMe2](μ-SPh)(μ-H) (2) has been synthesized in 66% yield by the reaction of Os3(CO)10(μ-SPh)(μ-H) with CH2-(NMe2)2. Photodecarbonylation of 2 leads to formation of the compound Os3(CO)8(μ-C=NMe2)(μ-SPh)(μ-H) (3) in 37% yield by an a-CH bond activation in the carbene ligand.

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U2 - 10.1021/om00140a037

DO - 10.1021/om00140a037

M3 - Article

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EP - 1925

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 9

ER -

Novel Ligand Transformations in Cluster Complexes. α-CH Bond Activation In a Secondary Carbene Ligand In a Triosmium Cluster

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