Optimization of Magnetic Filler Loading and Interstitial Dielectric Percolation for Tunable Triboelectric–Electromagnetic Hybrid Generators

In this study, a material-driven strategy is presented to realize tunable triboelectric–electromagnetic hybrid generators while overcoming the form-factor limitations of conventional magnet-assisted systems. A magneto-dielectric hybrid generator (MDHG) was constructed using a soft magnetized dielectric composite, where NdFeB microparticles were embedded in an Ecoflex matrix and activated by pulse magnetization, allowing a single compliant layer to operate simultaneously as a triboelectric contact medium and a magnetic flux source coupled to a coil. The magnetic filler loading was systematically optimized to elucidate the trade-off between enhanced electromagnetic induction and a non-monotonic triboelectric response governed by dielectric polarization, surface potential, and interfacial energetics. To selectively strengthen the triboelectric branch without sacrificing electromagnetic output, nanoscale BaTiO₃ was introduced as an interstitial dielectric phase to promote polarization-active pathways and suppress screening-driven charge-utilization loss. Under contact–separation operation, the optimized MDHG produced triboelectric outputs up to a V_OC of 400.40 V and I_SC of 56.95 μA, while the electromagnetic branch delivered up to a V_OC of 260.04 mV and I_SC of 0.89 mA, corresponding to 2.87- and 2.62-fold increases in triboelectric V_OC and I_SC over pristine Ecoflex. Finally, the hybrid signatures enabled a wearable smart-skin interface capable of decoupling touch occurrence, intensity, and counter-material identity.