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Photodissociation of nitrous oxide by slice ion imaging: The stagnation pressure dependence

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Abstract

Photodissociation of nitrous oxide near 203 nm has been studied by a combination of high resolution slice ion imaging technique and (2+1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy of N2(X1Σ+g) via the (a" Σ+g) state. We have measured the recoil velocity and angular distributions of N2 fragments by ion images of the state-resolved photofragments. The N2 fragments were highly rotationally excited and the NN-O bond dissociation energy was determined to be 3.635 eV. Also, we investigated the photofragment images from the photodissociation of N2O clusters with various stagnation pressures.

Original languageEnglish
Pages (from-to)2661-2664
Number of pages4
JournalBulletin of the Korean Chemical Society
Volume30
Issue number11
DOIs
Publication statusPublished - Nov 2009

Keywords

  • Cluster
  • Photodissociation
  • Slice ion imaging

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