Rhodium(NHC)-catalyzed amination of aryl bromides

Min Kim; Sukbok Chang

doi:10.1021/ol100437j

Rhodium(NHC)-catalyzed amination of aryl bromides

Min Kim
, Sukbok Chang

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

(Figure Presented) A rhodium-catalyzed amination reaction of aryl halides with amines has been developed with the use of a N-heterocyclic carbene (NHC) ligand (I/Pr = 1,3-diisopropylimidazol-2-ylidene). The active metal species responsible for the reaction progress was identified. The developed procedure of the Rh-catalyzedW-arylation is convenient to carry out under mild reaction conditions displaying a wide range of substrate scope and high degree of functional group tolerance.

Original language	English
Pages (from-to)	1640-1643
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	7
DOIs	https://doi.org/10.1021/ol100437j
Publication status	Published - 2 Apr 2010

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title = "Rhodium(NHC)-catalyzed amination of aryl bromides",

abstract = "(Figure Presented) A rhodium-catalyzed amination reaction of aryl halides with amines has been developed with the use of a N-heterocyclic carbene (NHC) ligand (I/Pr = 1,3-diisopropylimidazol-2-ylidene). The active metal species responsible for the reaction progress was identified. The developed procedure of the Rh-catalyzedW-arylation is convenient to carry out under mild reaction conditions displaying a wide range of substrate scope and high degree of functional group tolerance.",

author = "Min Kim and Sukbok Chang",

year = "2010",

month = apr,

day = "2",

doi = "10.1021/ol100437j",

language = "English",

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pages = "1640--1643",

journal = "Organic Letters",

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publisher = "American Chemical Society",

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T1 - Rhodium(NHC)-catalyzed amination of aryl bromides

AU - Kim, Min

AU - Chang, Sukbok

PY - 2010/4/2

Y1 - 2010/4/2

N2 - (Figure Presented) A rhodium-catalyzed amination reaction of aryl halides with amines has been developed with the use of a N-heterocyclic carbene (NHC) ligand (I/Pr = 1,3-diisopropylimidazol-2-ylidene). The active metal species responsible for the reaction progress was identified. The developed procedure of the Rh-catalyzedW-arylation is convenient to carry out under mild reaction conditions displaying a wide range of substrate scope and high degree of functional group tolerance.

AB - (Figure Presented) A rhodium-catalyzed amination reaction of aryl halides with amines has been developed with the use of a N-heterocyclic carbene (NHC) ligand (I/Pr = 1,3-diisopropylimidazol-2-ylidene). The active metal species responsible for the reaction progress was identified. The developed procedure of the Rh-catalyzedW-arylation is convenient to carry out under mild reaction conditions displaying a wide range of substrate scope and high degree of functional group tolerance.

UR - https://www.scopus.com/pages/publications/77950197548

U2 - 10.1021/ol100437j

DO - 10.1021/ol100437j

M3 - Article

C2 - 20205466

AN - SCOPUS:77950197548

SN - 1523-7060

VL - 12

SP - 1640

EP - 1643

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Rhodium(NHC)-catalyzed amination of aryl bromides

Abstract

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