Selective hydrogenolysis of CFC-113a by group VIII transition metal complexes

Ook Jae Cho; Ik Mo Lee; Kun You Park; Hoon Sik Kim

doi:10.1016/0022-1139(94)03159-W

Selective hydrogenolysis of CFC-113a by group VIII transition metal complexes

Ook Jae Cho
, Ik Mo Lee
, Kun You Park
, Hoon Sik Kim

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Highly efficient and selective hydrogenolysis of CFC-113a (CF₃CCl₃) to produce HCFC-123 (CF₃CHCl₂) has been achieved through the use of Group VIII transition metal complexes. The catalytic activity observed was sensitive to solvents and to the structures of the metal complexes.

Original language	English
Pages (from-to)	107-109
Number of pages	3
Journal	Journal of Fluorine Chemistry
Volume	71
Issue number	1
DOIs	https://doi.org/10.1016/0022-1139(94)03159-W
Publication status	Published - Mar 1995

Bibliographical note

Funding Information:
Financial support from research funds of Inha University (1993), KIST (Korea Institute of Science and Technology) (93HN-142) and HanKook Shinwha Co. is appreciated. O.-J.C. is also grateful for a fellowship of the Center for Molecular Structure-Reactivity (1991-1993).

Keywords

CFC-113a
Catalysis
Group VIII transition metal complexes
Selective hydrogenolysis
Selectivity

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10.1016/0022-1139(94)03159-W

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title = "Selective hydrogenolysis of CFC-113a by group VIII transition metal complexes",

abstract = "Highly efficient and selective hydrogenolysis of CFC-113a (CF3CCl3) to produce HCFC-123 (CF3CHCl2) has been achieved through the use of Group VIII transition metal complexes. The catalytic activity observed was sensitive to solvents and to the structures of the metal complexes.",

keywords = "CFC-113a, Catalysis, Group VIII transition metal complexes, Selective hydrogenolysis, Selectivity",

author = "Cho, \{Ook Jae\} and Lee, \{Ik Mo\} and Park, \{Kun You\} and Kim, \{Hoon Sik\}",

note = "Funding Information: Financial support from research funds of Inha University (1993), KIST (Korea Institute of Science and Technology) (93HN-142) and HanKook Shinwha Co. is appreciated. O.-J.C. is also grateful for a fellowship of the Center for Molecular Structure-Reactivity (1991-1993).",

year = "1995",

month = mar,

doi = "10.1016/0022-1139(94)03159-W",

language = "English",

volume = "71",

pages = "107--109",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

number = "1",

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TY - JOUR

T1 - Selective hydrogenolysis of CFC-113a by group VIII transition metal complexes

AU - Cho, Ook Jae

AU - Lee, Ik Mo

AU - Park, Kun You

AU - Kim, Hoon Sik

N1 - Funding Information: Financial support from research funds of Inha University (1993), KIST (Korea Institute of Science and Technology) (93HN-142) and HanKook Shinwha Co. is appreciated. O.-J.C. is also grateful for a fellowship of the Center for Molecular Structure-Reactivity (1991-1993).

PY - 1995/3

Y1 - 1995/3

N2 - Highly efficient and selective hydrogenolysis of CFC-113a (CF3CCl3) to produce HCFC-123 (CF3CHCl2) has been achieved through the use of Group VIII transition metal complexes. The catalytic activity observed was sensitive to solvents and to the structures of the metal complexes.

AB - Highly efficient and selective hydrogenolysis of CFC-113a (CF3CCl3) to produce HCFC-123 (CF3CHCl2) has been achieved through the use of Group VIII transition metal complexes. The catalytic activity observed was sensitive to solvents and to the structures of the metal complexes.

KW - CFC-113a

KW - Catalysis

KW - Group VIII transition metal complexes

KW - Selective hydrogenolysis

KW - Selectivity

UR - https://www.scopus.com/pages/publications/0000310810

U2 - 10.1016/0022-1139(94)03159-W

DO - 10.1016/0022-1139(94)03159-W

M3 - Article

AN - SCOPUS:0000310810

SN - 0022-1139

VL - 71

SP - 107

EP - 109

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 1

ER -

Selective hydrogenolysis of CFC-113a by group VIII transition metal complexes

Abstract

Bibliographical note

Keywords

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