Synthesis of Zn-MOF incorporating titanium-hydrides as active sites binding H2 molecules

Jongsik Kim; Dong Ok Kim; Dong Wook Kim; Kil Sagong

doi:10.1016/j.jssc.2015.06.034

Synthesis of Zn-MOF incorporating titanium-hydrides as active sites binding H₂ molecules

Jongsik Kim
, Dong Ok Kim
, Dong Wook Kim
, Kil Sagong

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

This paper describes the synthetic effort for a Zn-MOF imparting Ti-H as a preferential binding site potentially capturing H₂ molecules via Kubas-type interaction. The formation mechanism of Ti-H innate to the final material was potentially demonstrated to follow a radical dissociation rather than a β-hydrogen elimination and a C-H reductive elimination.

Original language	English
Pages (from-to)	110-117
Number of pages	8
Journal	Journal of Solid State Chemistry
Volume	230
DOIs	https://doi.org/10.1016/j.jssc.2015.06.034
Publication status	Published - 11 Jul 2015

Bibliographical note

Publisher Copyright:
© 2015 Elsevier Inc. All rights reserved.

Keywords

H adsorption
Kubas binding
Metal-organic framework
Post-synthetic modification
Site-isolation

Access to Document

10.1016/j.jssc.2015.06.034

Cite this

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title = "Synthesis of Zn-MOF incorporating titanium-hydrides as active sites binding H2 molecules",

abstract = "This paper describes the synthetic effort for a Zn-MOF imparting Ti-H as a preferential binding site potentially capturing H2 molecules via Kubas-type interaction. The formation mechanism of Ti-H innate to the final material was potentially demonstrated to follow a radical dissociation rather than a β-hydrogen elimination and a C-H reductive elimination.",

keywords = "H adsorption, Kubas binding, Metal-organic framework, Post-synthetic modification, Site-isolation",

author = "Jongsik Kim and \{Ok Kim\}, Dong and \{Wook Kim\}, Dong and Kil Sagong",

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journal = "Journal of Solid State Chemistry",

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AU - Kim, Jongsik

AU - Ok Kim, Dong

AU - Wook Kim, Dong

AU - Sagong, Kil

PY - 2015/7/11

Y1 - 2015/7/11

N2 - This paper describes the synthetic effort for a Zn-MOF imparting Ti-H as a preferential binding site potentially capturing H2 molecules via Kubas-type interaction. The formation mechanism of Ti-H innate to the final material was potentially demonstrated to follow a radical dissociation rather than a β-hydrogen elimination and a C-H reductive elimination.

AB - This paper describes the synthetic effort for a Zn-MOF imparting Ti-H as a preferential binding site potentially capturing H2 molecules via Kubas-type interaction. The formation mechanism of Ti-H innate to the final material was potentially demonstrated to follow a radical dissociation rather than a β-hydrogen elimination and a C-H reductive elimination.

KW - H adsorption

KW - Kubas binding

KW - Metal-organic framework

KW - Post-synthetic modification

KW - Site-isolation

UR - https://www.scopus.com/pages/publications/84936878462

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DO - 10.1016/j.jssc.2015.06.034

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VL - 230

SP - 110

EP - 117

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

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