The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol

Hoon Sik Kim; Hyunjoo Lee; Dai Ki Choi

The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol

Hoon Sik Kim, Hyunjoo Lee, Dai Ki Choi

Research output: Contribution to journal › Conference article › peer-review

Abstract

The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol was studied. Bu₂SnO and Bu₂Sn(C₁₁H₂₃CO₂) ₂ gave low yields of methyl phenyl carbonate and diphenyl carbonate. The use of triflic acid in conjunction with dibutyltin oxide significantly enhanced the activity of dibutyltin. Single crystal XRD study revealed that Bu₂Sn(OH)(OSO₂CF₃) was inactive intermediate species for the transesterification. This is an abstract of a paper presented at the 7th Annual Green Chemistry and Engineering Conference (Washington, D.C. 6/23-26/2003).

Original language	English
Journal	ACS Division of Environmental Chemistry, Preprints
Volume	44
Issue number	1
Publication status	Published - 2004
Event	EPA 19th Annual National Environmental Monitoring Conference - Arlington, VA, United States Duration: 21 Jul 2003 → 24 Jul 2003

Cite this

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title = "The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol",

abstract = "The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol was studied. Bu2SnO and Bu2Sn(C11H23CO2) 2 gave low yields of methyl phenyl carbonate and diphenyl carbonate. The use of triflic acid in conjunction with dibutyltin oxide significantly enhanced the activity of dibutyltin. Single crystal XRD study revealed that Bu2Sn(OH)(OSO2CF3) was inactive intermediate species for the transesterification. This is an abstract of a paper presented at the 7th Annual Green Chemistry and Engineering Conference (Washington, D.C. 6/23-26/2003).",

author = "Kim, {Hoon Sik} and Hyunjoo Lee and Choi, {Dai Ki}",

year = "2004",

language = "English",

volume = "44",

journal = "ACS Division of Environmental Chemistry, Preprints",

issn = "0093-3066",

publisher = "American Chemical Society",

number = "1",

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T1 - The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol

AU - Kim, Hoon Sik

AU - Lee, Hyunjoo

AU - Choi, Dai Ki

PY - 2004

Y1 - 2004

N2 - The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol was studied. Bu2SnO and Bu2Sn(C11H23CO2) 2 gave low yields of methyl phenyl carbonate and diphenyl carbonate. The use of triflic acid in conjunction with dibutyltin oxide significantly enhanced the activity of dibutyltin. Single crystal XRD study revealed that Bu2Sn(OH)(OSO2CF3) was inactive intermediate species for the transesterification. This is an abstract of a paper presented at the 7th Annual Green Chemistry and Engineering Conference (Washington, D.C. 6/23-26/2003).

AB - The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol was studied. Bu2SnO and Bu2Sn(C11H23CO2) 2 gave low yields of methyl phenyl carbonate and diphenyl carbonate. The use of triflic acid in conjunction with dibutyltin oxide significantly enhanced the activity of dibutyltin. Single crystal XRD study revealed that Bu2Sn(OH)(OSO2CF3) was inactive intermediate species for the transesterification. This is an abstract of a paper presented at the 7th Annual Green Chemistry and Engineering Conference (Washington, D.C. 6/23-26/2003).

UR - http://www.scopus.com/inward/record.url?scp=6344284586&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:6344284586

SN - 0093-3066

VL - 44

JO - ACS Division of Environmental Chemistry, Preprints

JF - ACS Division of Environmental Chemistry, Preprints

IS - 1

T2 - EPA 19th Annual National Environmental Monitoring Conference

Y2 - 21 July 2003 through 24 July 2003

ER -

The effect of sulfonate ligands in the Sn-catalyzed transesterification of dimethyl carbonate with phenol

Abstract

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