The structure, bonding and transformation behaviour of iminium, aminocarbene and aminocarbyne ligands in triosmium cluster complexes

Richard D. Adams; James E. Babin; Hoon Sik Kim

doi:10.1016/S0277-5387(00)86317-2

The structure, bonding and transformation behaviour of iminium, aminocarbene and aminocarbyne ligands in triosmium cluster complexes

Richard D. Adams
, James E. Babin
, Hoon Sik Kim

College of Sciences

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A summary of recent developments in the study of the reactions of tertiary amines with triosmium cluster complexes is presented. The relationships between iminium ion ligands, dimethylaminocarbene ligands and dimethylaminocarbyne ligands in several series of triosmium carbonyl cluster complexes are described. The transformations are dominated by binuclear CH activation processes. Novel ligand coordination modes were characterized by crystallographic methods.

Original language	English
Pages (from-to)	967-978
Number of pages	12
Journal	Polyhedron
Volume	7
Issue number	10-11
DOIs	https://doi.org/10.1016/S0277-5387(00)86317-2
Publication status	Published - 1988

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10.1016/S0277-5387(00)86317-2

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title = "The structure, bonding and transformation behaviour of iminium, aminocarbene and aminocarbyne ligands in triosmium cluster complexes",

abstract = "A summary of recent developments in the study of the reactions of tertiary amines with triosmium cluster complexes is presented. The relationships between iminium ion ligands, dimethylaminocarbene ligands and dimethylaminocarbyne ligands in several series of triosmium carbonyl cluster complexes are described. The transformations are dominated by binuclear CH activation processes. Novel ligand coordination modes were characterized by crystallographic methods.",

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year = "1988",

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T1 - The structure, bonding and transformation behaviour of iminium, aminocarbene and aminocarbyne ligands in triosmium cluster complexes

AU - Adams, Richard D.

AU - Babin, James E.

AU - Kim, Hoon Sik

PY - 1988

Y1 - 1988

N2 - A summary of recent developments in the study of the reactions of tertiary amines with triosmium cluster complexes is presented. The relationships between iminium ion ligands, dimethylaminocarbene ligands and dimethylaminocarbyne ligands in several series of triosmium carbonyl cluster complexes are described. The transformations are dominated by binuclear CH activation processes. Novel ligand coordination modes were characterized by crystallographic methods.

AB - A summary of recent developments in the study of the reactions of tertiary amines with triosmium cluster complexes is presented. The relationships between iminium ion ligands, dimethylaminocarbene ligands and dimethylaminocarbyne ligands in several series of triosmium carbonyl cluster complexes are described. The transformations are dominated by binuclear CH activation processes. Novel ligand coordination modes were characterized by crystallographic methods.

UR - https://www.scopus.com/pages/publications/0038462414

U2 - 10.1016/S0277-5387(00)86317-2

DO - 10.1016/S0277-5387(00)86317-2

M3 - Article

AN - SCOPUS:0038462414

SN - 0277-5387

VL - 7

SP - 967

EP - 978

JO - Polyhedron

JF - Polyhedron

IS - 10-11

ER -

The structure, bonding and transformation behaviour of iminium, aminocarbene and aminocarbyne ligands in triosmium cluster complexes

Abstract

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