Trivalent copper and indium heterometallic complex with dithiocarbamate and iodide ligands

Hyun−Jong J. Lee; Seonho Jung; Ji−Hyun H. Cha; Dongsik Nam; Wonyoung Choe; Duk−Young Y. Jung

doi:10.1016/j.molstruc.2019.127478

Trivalent copper and indium heterometallic complex with dithiocarbamate and iodide ligands

Hyun−Jong J. Lee
, Seonho Jung
, Ji−Hyun H. Cha
, Dongsik Nam
, Wonyoung Choe
, Duk−Young Y. Jung

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The heterometallic Cu–In complex salt [Cu(III) (dtc)₂][In(III)I₄](1) (dtc = S₂CNEt₂, diethyldithiocarbamate) was prepared by reactions of Cu(II) (dtc)₂ and In(III)I₃ in benzene solution. As a redox reaction, Cu(II) (dtc)₂ was oxidized to [Cu(III) (dtc)₂]⁺, and In(III)I₃ was changed to [In(III)I₄]⁻. The square−planar Cu(III)S₄ local symmetry of 1 involves a distorted octahedral coordination environment via long−range intermolecular interactions and represents a new one-dimensional structure of [Cu(III) (dtc)₂]⁺ units. The crystal packing system of 1 consists of many [Cu(III) (dtc)₂]⁺ chains surrounded by six parallel chains without solvent molecules. The infrared spectra of 1 showed a higher-frequency C–N thioureide bond in Cu(III) (dtc)₂ than that of pristine Cu(II) (dtc)₂, which has a lower oxidation state due to the Cu(II) center.

Original language	English
Article number	127478
Journal	Journal of Molecular Structure
Volume	1204
DOIs	https://doi.org/10.1016/j.molstruc.2019.127478
Publication status	Published - 15 Mar 2020

Bibliographical note

Publisher Copyright:
© 2019 Elsevier B.V.

Keywords

Copper
Dithiocarbamate
Heterometallic
Indium
Iodide
Trivalent

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10.1016/j.molstruc.2019.127478

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title = "Trivalent copper and indium heterometallic complex with dithiocarbamate and iodide ligands",

abstract = "The heterometallic Cu–In complex salt [Cu(III) (dtc)2][In(III)I4](1) (dtc = S2CNEt2, diethyldithiocarbamate) was prepared by reactions of Cu(II) (dtc)2 and In(III)I3 in benzene solution. As a redox reaction, Cu(II) (dtc)2 was oxidized to [Cu(III) (dtc)2]+, and In(III)I3 was changed to [In(III)I4]−. The square−planar Cu(III)S4 local symmetry of 1 involves a distorted octahedral coordination environment via long−range intermolecular interactions and represents a new one-dimensional structure of [Cu(III) (dtc)2]+ units. The crystal packing system of 1 consists of many [Cu(III) (dtc)2]+ chains surrounded by six parallel chains without solvent molecules. The infrared spectra of 1 showed a higher-frequency C–N thioureide bond in Cu(III) (dtc)2 than that of pristine Cu(II) (dtc)2, which has a lower oxidation state due to the Cu(II) center.",

keywords = "Copper, Dithiocarbamate, Heterometallic, Indium, Iodide, Trivalent",

author = "Lee, \{Hyun−Jong J.\} and Seonho Jung and Cha, \{Ji−Hyun H.\} and Dongsik Nam and Wonyoung Choe and Jung, \{Duk−Young Y.\}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2020",

month = mar,

day = "15",

doi = "10.1016/j.molstruc.2019.127478",

language = "English",

volume = "1204",

journal = "Journal of Molecular Structure",

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TY - JOUR

T1 - Trivalent copper and indium heterometallic complex with dithiocarbamate and iodide ligands

AU - Lee, Hyun−Jong J.

AU - Jung, Seonho

AU - Cha, Ji−Hyun H.

AU - Nam, Dongsik

AU - Choe, Wonyoung

AU - Jung, Duk−Young Y.

PY - 2020/3/15

Y1 - 2020/3/15

N2 - The heterometallic Cu–In complex salt [Cu(III) (dtc)2][In(III)I4](1) (dtc = S2CNEt2, diethyldithiocarbamate) was prepared by reactions of Cu(II) (dtc)2 and In(III)I3 in benzene solution. As a redox reaction, Cu(II) (dtc)2 was oxidized to [Cu(III) (dtc)2]+, and In(III)I3 was changed to [In(III)I4]−. The square−planar Cu(III)S4 local symmetry of 1 involves a distorted octahedral coordination environment via long−range intermolecular interactions and represents a new one-dimensional structure of [Cu(III) (dtc)2]+ units. The crystal packing system of 1 consists of many [Cu(III) (dtc)2]+ chains surrounded by six parallel chains without solvent molecules. The infrared spectra of 1 showed a higher-frequency C–N thioureide bond in Cu(III) (dtc)2 than that of pristine Cu(II) (dtc)2, which has a lower oxidation state due to the Cu(II) center.

AB - The heterometallic Cu–In complex salt [Cu(III) (dtc)2][In(III)I4](1) (dtc = S2CNEt2, diethyldithiocarbamate) was prepared by reactions of Cu(II) (dtc)2 and In(III)I3 in benzene solution. As a redox reaction, Cu(II) (dtc)2 was oxidized to [Cu(III) (dtc)2]+, and In(III)I3 was changed to [In(III)I4]−. The square−planar Cu(III)S4 local symmetry of 1 involves a distorted octahedral coordination environment via long−range intermolecular interactions and represents a new one-dimensional structure of [Cu(III) (dtc)2]+ units. The crystal packing system of 1 consists of many [Cu(III) (dtc)2]+ chains surrounded by six parallel chains without solvent molecules. The infrared spectra of 1 showed a higher-frequency C–N thioureide bond in Cu(III) (dtc)2 than that of pristine Cu(II) (dtc)2, which has a lower oxidation state due to the Cu(II) center.

KW - Copper

KW - Dithiocarbamate

KW - Heterometallic

KW - Indium

KW - Iodide

KW - Trivalent

UR - https://www.scopus.com/pages/publications/85076216485

U2 - 10.1016/j.molstruc.2019.127478

DO - 10.1016/j.molstruc.2019.127478

M3 - Article

AN - SCOPUS:85076216485

SN - 0022-2860

VL - 1204

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

M1 - 127478

ER -

Trivalent copper and indium heterometallic complex with dithiocarbamate and iodide ligands

Abstract

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Keywords

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