Tuning of interfacial HGO@CLS nanohybrid S-scheme heterojunction with improved carrier separation and photocatalytic activity towards RhB degradation

Herein, we premeditated and invented the innovative hybrid photocatalyst 2D/2D CuLa₂S₄ on holey graphene oxide (HGO) (HGO@CLS) via the hydrothermal method. Electrochemical techniques demonstrate the action of HGO in the HGO@CLS photocatalyst as an effective medium for electron transfer. Combining bimetallic sulfides on porous HGO synergistically provides a higher negative conduction band edge (−0.141 V), greater photo response (10.8 mA/cm²), smaller charge transfer resistance (R_ct = 1.79Ω), and lower photoluminescence (PL) spectral intensity. According to our research, the catalytic recitals are sped up when HGO is assimilated into CLS photocatalyst hetero-junction. Additionally, it lowers the reassimilation rate due to the combined mesh nanostructures and functionality of CLS and HGO. UV–Vis DRS, Mott-Schottky, PL, and Electrochemical impedance spectra (EIS) results manifested that the CuLa₂S₄/HGO makes the spatial separation competent and transference of charge carriers due to the photon irradiation and exhibits superior photocatalytic ability. Electron spin resonance (ESR) analysis confirmed that •OH and h⁺ were the predominant radical species responsible for Rhodamine B(RhB) degradation. Moreover, conceivable degradation ways of RhB were deduced according to the identified intermediates which are responsible for the degradation of recalcitrant products. To check the stability of the photocatalyst, revival tests were also carried out. Similarly, the oxidative byproducts created in the deprivation courses were looked at, and a thorough explanation for the mechanism of degradation was given.