Unlocking veiled oxygen redox in Na-based earth-abundant binary layered oxide

Oxygen-redox reactions (ORRs) in Na-based transition metal (TM) layered oxides have attracted a great deal of attention as a means of overcoming the intrinsic low energy density of the cathodes of sodium-ion batteries (SIBs), because their activities occur above ≈4.0 VversusNa⁺/Na and deliver extra capacity beyond the TM-based redox contribution. Intriguingly, Mn-based binary-layered oxides (e.g., Na_1−x[Mn_1−yNi_y]O₂), have recently been re-examined to elucidate the ORR involvement that had been assigned to the Ni³⁺/Ni⁴⁺redox couple. Accordingly, Na_1−x[Mn_1/2Fe_1/2]O₂, a representative abundant cathode, was reinvestigated in detail using first-principles calculations to unlock veiled ORRs upon charging. First, the charge variations of Mn, Fe, and O showed that a typical Mn³⁺/Mn⁴⁺cationic redox is a principal factor in charge compensation for 0.25 ≤x≤ 0.5 in Na_1−x[Mn_1/2Fe_1/2]O₂, whereas a dominant ORR contributes to the charge compensation with the partial Fe redox for a value abovex= 0.5. Second, the ORR is selective depending on the oxygen site coordinates with Fe-rich (2Fe-O-Mn) or Mn-rich (Fe-O-2Mn) environments. Third, the Fe-O chemical bonding features reveal that the Jahn-Teller distortion determines the priority of the oxygen redox reaction ≈4.0 V. Along these lines, our findings provide insights into directions in utilizing the veiled oxygen redox reaction of Na_x[Mn_1−yFe_y]O₂binary oxides.